Hi all,
Ok so say I use oyster shell in my tank to raise the kh to 4 (I know it can be higher but I will use 4 as an example) and I do a 50% water change with my tapwater that has a kh of approx 1 (I'm being generous saying 1. It is that low) would that kill off my livestock? I know oyster shell is slow acting and doing a 10% change wouldn't make any difference but a 50% would?
No, it should be fine, you will still get relatively slow changes in water chemistry. HCO3- is a "weak base", and in equilibrium with CO2 (as H2CO3-) a weak acid, so this is a "buffered system".
I simply add bicarbonate of soda from a supermarket to get a KH of 5. Have done it for years with no problems and you soon get to used to getting the dose right.
Sodium bicarbonate (NaHCO3) works just as well to raise dKH. The only reason for preferring potassium bicarbonate (KHCO3) is that the potassium ion (K+) will be taken up by the plants, whilst the sodium ion (Na+) won't. This is why the sea is salty with 99% NaCl, plants don't have much requirement for either Na+ or Cl- ion so they have a very long residence time in the sea water.
I used to use bicarbonate of soda years ago when I was keeping discus. Do you find that the kh drops during the week? I found bicarb to have a temporary effect on kh and ph.
You can exhaust the HCO3- ions, it is because NaHCO3 full disassociates, so you have no reserve of ions (the system isn't "buffered").
This isn't as relevant for planted tank keepers, and if you are changing 50% of the water every week, its just not going to happen. There is an explanation at the excellent
<"Skeptical aquarist - Bio-acidification">.
That is also one advantage of the coral gravel/shell grit approach, you have a reserve ("buffer") of "insoluble" CaCO3.
Hope that makes sense.
If you are using EI you can just add KHCO3 with the rest of your salts. 3.6g KHCO3 in 25 litres is 4dKH.
cheers Darrel