Have you wormed the tank? Or noticed white stringy faeces? If so, I'd definately suggest a Flubenol treatment. Also, do you only have the three? It could be that the one that has turned black has been the victim of bullying-they are chichlids after all. They're best kept in groups of 6 or more, because this means that bullying is not concentrated on one individual, although it's not advisable to add anymore until the disease is cleared up. For now, I would start with a Flubenol treatment, with large water changes to keep the water spot on, and keep feeding as normal. I'd lesson the hours the lights are on to try and minimise stress also. I'm assuming you keep them at roughly 29 deg, but it might be worth raising this to to 31-32 slowly. Hope this helps!