Hi all,
Is low pH not a problem because ammonia is usually ammonium under these circumstances? Even if you had a wet/dry filter with more oxygenation - does pH have no effect on bacteria?
Yes pH has an effect on the ammonia oxidising bacteria that were thought to be responsible for nitrification in aquariums. This article is by Dr Tim Hovanec, <"
Bacteria revealed">, and it summarize what we know now. This is the paper which first indicated that the Archaea are the primary oxidising organisms in aquariums: <"
Aquarium Nitrification Revisited: Thaumarchaeota Are the Dominant Ammonia Oxidizers in Freshwater Aquarium Biofilters">. The Archaea are much less constrained by low pH, but they still need a source of CO2 (usually from dissolved HCO3-).
All decomposition is slowed in acidic water, if you put dead leaves into a fish tank with oxygenated alkaline water they will much more quickly oxidise via bacterial activity, when compared with a tank with acidic water.
This is the pH response curve of total ammoniacal ammonia (TAN). Oxygen becomes quite relevant here, because it is a base, and even water that is naturally acidic may become alkaline if oxygen saturation is at, or above, 100%, so there are risks involved in assuming pH will protect your livestock.

It is really back to plants again, plants are a massive plus in biological filtration, they really are the <"
goose that lays the golden egg">, and a lot of this is to do with their positive effect on oxygen levels.
As long as the oxygen supply exceeds the oxygen demand biological filtration will carry on at any pH level. Plants give you "belt and braces" and particularly plants with access to aerial levels of CO2 and dissolved oxygen.
The ideal situation is to have emergent plants, because these engender more suitable conditions in the substrate for microbial colonisation, but floating plants are a very good alternative and their root structure still supports microbial activity, as well as the direct uptake of NH4+ from solution (details in the quoted text).
From Gilroy, S & Jones, L. (2000) "Through form to function: root hair development and nutrient uptake"
Trends in Plant Science, 5:2, pp56–60.
Available at <
http://www.sciencedirect.com/science/article/pii/S1360138599015514>
cheers Darrel