Hi all,
Yes, you can't cap it with sand, it is much too light and always ends up on top. I think it looks OK on its own. Calcined substrates are always likely to be reddish, because most sediments contain Iron (Fe), and when you heat them the iron it is oxidised to Iron III oxide (Fe2O3), the hydrated form of which is better known as "rust".
The characteristic that these substrates have in common is the ability to exchange positively charged ions (Mg2+, K+ etc.), expressed as their "Cation Exchange Capacity" (CEC), usually a substance with a high CEC will also have a high Anion Exchange Capacity (AEC), exchanging ions like NO3-, PO4- etc as well.
In the case of cat litter it is "Moler clay", an impure form of "Diatomaceous earth", the fossil remnants of marine diatoms, mixed with bentonite clays (from volcanic ash). The typical chemical composition for Diatomaceous Earth is about 80 to 90% silica, 2 to 4% alumina (attributed mostly to clay minerals), 0.5 to 2% iron oxide and a CEC approx. 25 - 30 meq/100g. <
http://www.inex.fi/english/company/supplier/damolin.php>. The bentonite is a Kaolonite 1:1 montmorillonite clay
which will have a very high CEC (aprox. 100 meq/100g). These values will be reduced by heating, but as the cat litter is calcined at a lowish temperature it should retain a reasonable CEC.
The nutrients held by the exchange sites will so some extent mirror the ions in solution, so if you soak the cat litter in a dilute solution of potassium nitrate (KNO3), the exchange sites will mainly be occupied by K+ and NO3- ions.
All ions have to be in solution before the plant can take them up, but the water in the substrate will be constantly being mixed with the water in the water column, so it really doesn't matter whether you add the nutrient to the water column or substrate.
cheers Darrel