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KNO3 or calcium ammonium nitrate?

hasan66

Member
Joined
22 Sep 2023
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225
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Türkiye
Hi I opened a topic and the plants were losing color. I proved that this is caused by potassium nitrate. Now I use calcium ammonium nitrate and the colors of the plants started to improve. By the way, I reduced the potassium fertilizer. Only the potassium from ro mineral is 6ppm. I do not observe any potassium deficiency.
 
I did the preparation as follows: 0.7 ppm calcium ammonium nitrate, 0.068 ppm urea. I wanted to give you the information that it will take a little more time, currently 1 week.
 
the difference
 

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Hi all,
Now I use calcium ammonium nitrate and the colors of the plants started to improve
That should be all right. It will be interesting to see how you get on.

I would be pretty wary of the <"ammonia / ammonium (NH3 / NH4+) content"> for any one who has fish. The formula is 5Ca(NO3)2.NH4NO3.10H2O.

cheers Darrel
 
Hi all,

That should be all right. It will be interesting to see how you get on.

I would be pretty wary of the <"ammonia / ammonium (NH3 / NH4+) content"> for any one who has fish. The formula is 5Ca(NO3)2.NH4NO3.10H2O.

cheers Darrel
I think seachem and tropica use nh4 and I have also seen people use these fertilizers in tanks with fish. I really don't know what makes ammonium so dangerous.
 
It’s the Un-Ionised form NH3 (Ammonia) that’s is most toxic.

Total ammonia in aqueous solution consists of two principal forms, the ammonium ion (NH4+) and un-ionised ammonia (NH3), with relative concentrations being pH- and temperature-dependent. The un-ionised form is most toxic due the fact that it is uncharged and lipid soluble and thus traverses biological membranes more readily than the charged and hydrated NH4+ ions (Wuhrmann and Woker, 1948, Downing and Merkens, 1955).

The effect of pH variation at the ammonium/ammonia equilibrium in wastewater and its toxicity to Lemna gibba


:)
 
I proved that this is caused by potassium nitrate
Well nothing was really proven, or dis proven. Certainly not in the context of the original post, which peeps should be aware of.

i think seachem and tropica use nh4
Seachem tend to opt for Urea, Tropica use some ammonium (NH4) blend.

Either way I'm glad that within the space of a "few days" the problems of the tank seem to have been fixed, is the cure NH4, reduced potassium or something else?
 
Well nothing was really proven, or dis proven. Certainly not in the context of the original post, which peeps should be aware of.


Seachem tend to opt for Urea, Tropica use some ammonium (NH4) blend.

Either way I'm glad that within the space of a "few days" the problems of the tank seem to have been fixed, is the cure NH4, reduced potassium or something else?
John, whenever I used potassium nitrate, I observed stunting in the plants and BGA in the leaves, but calcium ammonium nitrate did not cause such problems, from now on I will only use calcium nitrate or magnesium nitrate and see what happens.
 
whenever I used potassium nitrate, I observed stunting in the plants and BGA in the leaves, but calcium ammonium nitrate did not cause such problems
Well, all factors influence the outcome in their interactive complexity. You have changed one variable, and it brought positive results. But in different circumstances, the same action may lead to quite different outcome. This is because you don't take into account other variables.
Your experience suggests - and I stress the word 'suggests' - that there was too much potassium in your tank relative to calcium and magnesium. With the change of your fertilizer, you have improved the ratios of those three. Probably. We'd need reasonably precise measurements of all elements in question, and even then, it would only strongly suggest that this is the case. Such a scenario is in line with science, so it presents itself as a plausible explanation. However, it's still quite possible that yet other factors were at play in your case.

I'm studying these relations for years, and the more I know, the less I'm inclined to use the words "proof", "proved".
 
Well nothing was really proven, or dis proven. Certainly not in the context of the original post, which peeps should be aware of.


Seachem tend to opt for Urea, Tropica use some ammonium (NH4) blend.

Either way I'm glad that within the space of a "few days" the problems of the tank seem to have been fixed, is the cure NH4, reduced potassium or something else?
Sounds like a combination of nh4 and no3 to me
 
Hi all,
the ammonium ion (NH4+) and un-ionised ammonia (NH3), with relative concentrations being pH- and temperature-dependent. The un-ionised form is most toxic due the fact that it is uncharged and lipid soluble and thus traverses biological membranes more readily than the charged and hydrated NH4+ ions
I really don't know what makes ammonium so dangerous.
What @X3NiTH says, you also have the nitrite ion (NO2-) to consider <"Nitrite Toxicosis In Freshwater Fish or Brown Blood Disease">.

We know more about nitrification now than when that article was written and subsequently COMAMMOX Nitrospira have been found to be common in aquariums - <"Correspondence with Dr Ryan Newton - School of Freshwater Sciences, University of Wisconsin—Milwaukee">, but NO2- poisoning is still a risk.
pH 5.8 gave me cold water
I tend to use <"TAN (Total Ammoniacal Nitrate) as a concept"> rather than treating NH3 and NH4+ as separate entities. In low conductivity water pH is inherently unstable and depletion of CO2 can lead to rapid pH rise <"A question, dissolved oxygen and a pond"> and your "safe" NH4+ becomes NH3.

cheers Darrel
 
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On your original issue, did you add/increase remineralizer (Ca/Mg) or iron at any point? My plants go white like that without calcium/magnesium or iron. Excess potassium causes leaves to curl inwards. Excess nitrogen causes algae... also I'm not an expert on fish, but your type of fish need hard water, no?
 
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