Clearly this is approximate as there is clearly something else in your water adding to KH and/or altering pH, as reading at the end of the table in Toms link, 16KH water with no CO2 will have a pH of greater than 8.6 and yours isn't.
What is in the water will not affect the pH drop very much even if it affects the starting pH. So dont worry if you dont see the starting pH matching that on the table for "your" kH. 1 pH drop will still be aprox=30 ppm of co2. This is the same as saying forget about your kH because you really dont know it.
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